Ian Rae

Radiocarbon Dating at the Museum of Applied ScienceVictoria 1952-70: a Pioneer Venture

Ian D Rae

Journal article  |  2018  |  Historical Records of Australian Science

James Douglas Morrison 1924-2013

Ian D Rae

Journal article  |  2018  |  Historical Records of Australian Science

Editors' Page

Sara Maroske, Ian D Rae

Journal article  |  2017  |  Historical Records of Australian Science

John Melvin Swan 1924-2015

David J Collins, Ian D Rae

Journal article  |  2017  |  Historical Records of Australian Science

Editors' Page

Sara Maroske, Ian D Rae

Journal article  |  2017  |  Historical Records of Australian Science

Elemental Micro-analysis of Organic Compounds: the Australian Experience

Ian D Rae

Journal article  |  2016  |  Historical Records of Australian Science

Ideal gases: anaesthetics in the heart of the twentieth century

I RAE

Conference Proceedings  |  2016

Substance Abuse: Carbon Tetrachloride and the Ozone Layer

Ian D Rae

Journal article  |  2016  |  Australian Journal of Chemistry

Theory versus Practice in the Twentieth-Century Search for the Ideal Anaesthetic Gas

Ian D Rae

Journal article  |  2016  |  Ambix

Elemental micro-analysis of organic compounds. The Australian experience.

I RAE

Journal article  |  2016  |  Historical Records of Australian Science

Direct detection of brominated flame retardants from plastic e-waste using liquid extraction surface analysis mass spectrometry

Martin RL Paine, Ian D Rae, Stephen J Blanksby

Journal article  |  2014  |  Rapid Communications in Mass Spectrometry

Vitamin A and Australian Fish Liver Oils

Ian D Rae

Journal article  |  2014  |  Historical Records of Australian Science

The Trouble with Bromine: Health and Environmental Impacts of Organobromine Compounds

Ian D Rae

Journal article  |  2014  |  Global Environment

William Gilbert Mixter (1846-1936): a Yale Chemist who Deserves to be Remembered

ID RAE

Journal article  |  2014  |  Bulletin for the history of chemistry / Division of the History of Chemistry of the American Chemical Society

Indigo Dreaming

Ian D Rae

Journal article  |  2014  |  Australian Journal of Chemistry

David Orme Masson, the Periodic Classification of the Elements and His 'Flap' Model of the Periodic Table

Ian D Rae

Journal article  |  2013  |  Historical Records of Australian Science

Liebig’s Australian Connection: James King’s Scientific Viticulture

ID Rae, WH Brock

Journal article  |  2013  |  Historical Records of Australian Science

Liebig's Australian Connection: James King's Scientific Viticulture

Ian D Rae, William H Brock

Journal article  |  2013  |  Historical records of Australian Science

Athelstan Laurence Johnson Beckwith OA FAA. 20 February 1930 — 15 May 2010

Ian D Rae

Journal article  |  2012  |  Biographical Memoirs of Fellows of the Royal Society

Athelstan Laurence Johnson Beckwith 1930-2010

Ian D Rae

Journal article  |  2012  |  Historical Records of Australian Science

Archibald Liversidge, FRS: Imperial Science under the Southern Cross.

Ian D Rae

Journal article  |  2010  |  HISTORICAL RECORDS OF AUSTRALIAN SCIENCE

Marine Pharmacology in Australia. The Roche Research Institute at Dee Why, New South Wales, 1974-81

Ian D Rae

Journal article  |  2010  |  Australian Journal of Chemistry

The Roche Research Institute of Marine Pharmacology, 1974-1981: Searching for Drug Leads from Australian Marine Organisms

Ian D Rae

Journal article  |  2009  |  Historical Records of Australian Science

Banned Solvents

Ian D Rae

Journal article  |  2009  |  Journal of Chemical Education

Managing the intractable: Communicative structures for management of hexachlorobenzene and other scheduled wastes

Ian Rae, Paul Brown

Journal article  |  2009  |  Journal of Environmental Management

Geoffrey Malcolm Badger 1916–2002

ID Rae

Journal article  |  2009  |  Historical Records of Australian Science

Geoffrey Malcolm Badger 1916-2002

Ian D Rae

Journal article  |  2009  |  Historical Records of Australian Science

Anticipating Tomorrow Defence Needs: A Century of Australian Defence Science

Ian Rae

Journal article  |  2008  |  HISTORICAL RECORDS OF AUSTRALIAN SCIENCE

RWE MacIvor: Late-nineteenth-century Advocate for Scientific Agriculture in South-eastern Australia

David J Collins, Ian D Rae

Journal article  |  2008  |  Historical Records of Australian Science

Chemistry @ Melbourne 1960-2000

Ian Rae

Journal article  |  2008  |  HISTORICAL RECORDS OF AUSTRALIAN SCIENCE

High tech trash: Digital devices, hidden toxics, and human health

Ian Rae

Journal article  |  2008  |  Minerva

Something in the air: connections between global warming, ozone depletion, POPs and particulates

Ian D Rae

Journal article  |  2008  |  Environmental Chemistry

R.W. E. MacIvor: Late-nineteenth-century Advocate for Scientific Agriculture in South-eastern Australia

ID Rae

Journal article  |  2008  |  Historical Records of Australian Science

Appointing a professor: Reflections on filling the chair of organic chemistry at the University of Sydney in 1948

Ian D Rae

Journal article  |  2007  |  Historical Records of Australian Science

The technology of whaling: Why they did it and how

I RAE

Book Chapter  |  2007

Walter Moritz Boas (1904-1982) - scientist

I RAE

Scholarly edition  |  2007

Denis Fletcher Kelsall (1918-1982) - chemical engineer

I RAE

Scholarly edition  |  2007

Robert Rutherford Blackwood (106-1982) - businessman and professor of engineering

I RAE

Scholarly edition  |  2007

All environmental politics is local?

Ian D Rae

Journal article  |  2006  |  Minerva - an internet journal of philosophy

The effects of fluorine and chlorine substituents across the fjords of bifluorenylidenes: Overcrowding and stereochemistry

Sergey Pogodin, Ian D Rae, Israel Agranat

Journal article  |  2006  |  European Journal of Organic Chemistry

Ozonised oils as disinfectants.

Ian D Rae

Journal article  |  2006  |  Ambix

In the ozone fervour of the mid-nineteenth century, the ability of ether, turpentine, and other unsaturated oils to take up oxygen..

Rackarock: On the path from black powder to ANFO

I RAE, JH Whitehad

Book Chapter  |  2006

Chemistry in Australia: Growing Up Down Under

ID RAE

Journal article  |  2005  |  Ambix

Granville Perkins and Leprosy Chemotherapy

ID RAE

Journal article  |  2005  |  Bulletin for the History of Chemistry

Mining and Using Arsenic in Australia

ID RAE

Journal article  |  2004  |  Icon

Alternative technologies for destruction of PCB and other POPs

ID RAE

Book Chapter  |  2003

Federalism in the regulation of chemical pollutants in Australia

ID Rae

Journal article  |  2003  |  Prometheus

False start for the PhD in Australia

ID Rae

Journal article  |  2002  |  Historical Records of Australian Science

When the PhD was introduced in England, consideration was also being given to its introduction in Australia. The University of Mel..

Gold and arsenic in Victoria's mining history

ID RAE

Journal article  |  2001  |  Victorian Historical Journal

Development of the acid and fertiliser industry in 19th century New Zealand: business networks and government rewards

ID RAE, JF LACK

Book Chapter  |  2001

Managing waste organochlorine chemicals in Australia

ID RAE

Journal article  |  2001  |  Environmental Politics

Managing waste organochlorine chemicals in Australia

ID Rae

Journal article  |  2001  |  Environmental Politics

More than bugs and stones: Chemistry in the Royal Society of New South Wales

AT Baker, ID Rae

Journal article  |  2000  |  Historical Records of Australian Science

Emil Votoček (1872-1950): A Tribute to the Czech Chemist-Composer-Lexicographer

GB Kauffman, F Jursik, ID Rae

Journal article  |  1999  |  Journal of Chemical Education

Emil Votocek (1872-1950): A tribute to the Czech chemist-composer-lexicographer

GB Kauffman, F Jursik, ID Rae

Journal article  |  1999  |  JOURNAL OF CHEMICAL EDUCATION

They had to go: Australian chemists who took doctor of philosophy degrees in Britain, 1945-1965

ID Rae

Journal article  |  1998  |  Historical Records of Australian Science

Relative signs of three-bond fluorine-carbon and four-bond fluorine-hydrogen couplings in 2-substituted fluorobenzenes

ID Rae, JA Weigold, DG De Kowalewski, RR Biekofsky, RH Contreras

Journal article  |  1996  |  Magnetic Resonance in Chemistry

Structure and in vivo activity of hypoglycaemic analogues of human growth hormone (6-13).

P Thompson, N Lim, NJ Ede, FM Ng, ID Rae, MT Hearn

Journal article  |  1995  |  Drug Design and Discovery

A range of peptide analogues related to Asu11-human growth hormone (6-13) have been synthesized and tested for hypoglycaemic activ..

Chemical organizations in Australia and New Zealand.

ID Rae

Journal article  |  1995  |  Ambix

Synthesis and conformation of constrained peptides with hypoglycaemic activity derived from human growth hormone.

NJ Ede, ID Rae, MT Hearn

Journal article  |  1994  |  International Journal of Peptide and Protein Research

The alpha-aminosuccinimide (Asu11) octapeptide analogue of human growth hormone hGH[6-13] (Leu6-Ser-Arg-Leu-Phe-Asu-Asn-Ala13) has..

Proximity effects on nuclear spin-spin coupling constants. 1. 1J(CH) couplings in the vicinity of an atom bearing lone pairs

C Vizioli, MC De Ruiz Azúa, CG Giribet, RH Contreras, L Turi, JJ Dannenberg, ID Rae, JA Weigold, M Malagoli, R Zanasi, P Lazzeretti

Journal article  |  1994  |  The Journal of Physical Chemistry

Synthesis of Methyl (Z)- and (E)-2-Methyl-(3-D)propenoates and Their Incorporation Into Polymethacrylates

HH Keah, ID Rae

Journal article  |  1993  |  Australian Journal of Chemistry

Methyl (E)- and (Z)-2-methyl(3-D) propenoates were prepared from (E)-3-bromo-2-methylpro- penoic acid. Polymerization by free r..

Vicinal c-h coupling as an aid to stereochemical assignments in substituted propenoic acids

HH Keah, ID Rae

Journal article  |  1993  |  Australian Journal of Chemistry

Two isomeric pairs of 3-bromopropenoic acids were prepared and vicinal C-H couplings were measured in their 13C n.m.r. spectra. Co..

Analysis of long‐range through‐space couplings via an intramolecular hydrogen bond

ID Rae, JA Weigold, RH Contreras, RR Biekofsky

Journal article  |  1993  |  Magnetic Resonance in Chemistry

E.S.R. Spectra of free radicals relevant to methacrylate polymerization

H Hong Keah, ID Rae

Journal article  |  1992  |  Australian Journal of Chemistry

Carbon-based free radicals were generated by thermal cleavage of the tetraester Me2C(COOME)-CH2-CMe( COOMe )- CMe ( COOMe )-CH2-..

Chemical design of peripherally acting compounds.

WR Jackson, FC Copp, JD Cullen, FJ Guyett, ID Rae, AJ Robinson, H Pothoulackis, AK Serelis, M Wong

Journal article  |  1992  |  Clinical and Experimental Pharmacology and Physiology

1. Some guanidines, related in structure to mianserin and to 2-methyl-1,2,9,13b-tetrahydro-3H-dibenz[c,f]imadazo[1,5a] azepin-3-im..

THE ADMIRAL'S STORM GLASS: Coffee‐table renaissance of an old weather instrument

HC Bolton, ID Rae

Journal article  |  1992  |  Weather

Signs of 19F1H and 19F13C spin–spin coupling constants mainly transmitted through space

ID Rae, JA Weigold, RH Contreras, G Yamamoto

Journal article  |  1992  |  Magnetic Resonance in Chemistry

Synthesis and evaluation of constrained peptide analogues related to the N-terminal region of human growth hormone.

NJ Ede, N Lim, ID Rae, FM Ng, MT Hearn

Journal article  |  1991  |  Peptide research

The synthesis and incorporation of two different isomeric gamma-lactam structures into peptide analogues related to hGH [6-13] are..

Conformations in solution of four 2,4,5,7‐tetramethyloctane‐4,5‐dicarboxylates: Molecular mechanics and NMR studies

KA Holland, ID Rae, JA Weigold

Journal article  |  1991  |  Magnetic Resonance in Chemistry

Chiral synthesis of a new protected γ-lactam bridged dipeptide

NJ Ede, ID Rae, MTW Hearn

Journal article  |  1991  |  Australian Journal of Chemistry

Fluorine deshielding in the proximity of a methyl group. An experimental and theoretical study

GW Gribble, DJ Keavy, ER Olson, ID Rae, A Staffa, TE Herr, MB Ferraro, RH Contreras

Journal article  |  1991  |  Magnetic Resonance in Chemistry

Identification of the aspartimide structure in a previously-reported peptide.

VM Robson, ID Rae, F Ng

Journal article  |  1990  |  Biological Chemistry Hoppe-Seyler

The octapeptide Leu-Ser-Arg-Leu-Phe-Asp-Asn-Ala (hGH 6-13) has been reported to show insulin-potentiating properties, and its synt..

Dimethyl cis- and trans-1, 2-dimethyl-cyclohexane-1, 2-dicarboxylate

ID Rae, AK Serelis

Journal article  |  1990  |  Australian Journal of Chemistry

1-Methoxy-3-trimethylsilyloxybuta-1,3-diene adds readily to dimethylmaleic anhydride, and the product can be converted into dim..

LETS HAVE MORE BORODIN

ID RAE

Journal article  |  1990  |  Leonardo

Synthesis of a new protected lactam-bridged dipeptide

NJ Ede, ID Rae, MTW Hearn

Journal article  |  1990  |  Tetrahedron Letters

Thermal Degradation of Polymers and Polymer Models. V A Model for Copoly(styrene- methyl methacrylate)

GD Fallon, KA Holland, ID Rae

Journal article  |  1990  |  Australian Journal of Chemistry

The synthesis of (�)- and meso-dimethyl 2,3-dimethyl-2,3-bis(2′-methyl-2′-phenylpropyl)butane-dioate from methyl 2,4-dimethyl-4-..

Relaxation processes in the n-methyl group of 1, 2, 2, 6, 6-pentamethylpiperidine

ID Rae, ML Woolcock

Journal article  |  1990  |  Australian Journal of Chemistry

Relaxation times (T1) and methyl-methyl nuclear Overhauser effects were measured for 1H, 13C and 2H nuclei in 1,2,2,6,6-pentameth..

Relaxation processes in aromatic methyl groups. ii: Methyl-methyl nuclear overhauser enhancements

ML Baron, LL Martin, ID Rae, PM Simmonds, ML Woolcock

Journal article  |  1990  |  Australian Journal of Chemistry

A range of compounds with methyl groups disposed ortho and peri on heteroaromatic frameworks have been prepared, and T1 values..

The research in organic chemistry of Aleksandr Borodin (1833-1887)

ID Rae

Journal article  |  1989  |  Ambix

Seed dispersal by ants: behaviour-releasing compounds in elaiosomes

CR Brew, DJ O'Dowd, ID Rae

Journal article  |  1989  |  Oecologia

ISOLATION OF OPIATE RECEPTOR LIGANDS IN COFFEE

KN WYNNE, M FAMILARI, JH BOUBLIK, OH DRUMMER, ID RAE, JW FUNDER

Journal article  |  1987  |  Clinical and Experimental Pharmacology and Physiology

Thermal degradation of polymers and polymer models. IV Thermolysis of a polymethacrylate model with an unsaturated end group

GR Morrow, ID Rae

Journal article  |  1987  |  Australian Journal of Chemistry

Thermal degradation of a model for the 'unsaturated end group' of poly(methyl methacrylate ) gives products which suggest that ho..

Thermal degradation of polymers. III thermal degradation of a compound which models the head-to-head linkage in poly(methyl methacrylate)

ID Rae

Journal article  |  1987  |  Australian Journal of Chemistry

As a model for a poly(methyl methacrylate ) chain which contains a head-to-head unit, the thermal degradation of tetramethyl 2,4,..

Detection and measurement of fluoroacetate in plant extracts by 19F NMR

ML Baron, CM Bothroyd, GI Rogers, A Staffa, ID Rae

Journal article  |  1987  |  Phytochemistry

The structure of papaverine in solution as determined by H nuclear magnetic relaxation methods

ID Rae, RM Simmonds

Journal article  |  1987  |  Australian Journal of Chemistry

Hydrogen relaxation in the papaverine molecule in CDCl3 solution has been studied so as to derive the conformation about the C1-..

Relaxation processes in aromatic methly groups. II—Methyl hydrogen T1 values for some halo‐toluenes and ‐xylenes

ID Rae, FB Sandbach

Journal article  |  1987  |  Magnetic Resonance in Chemistry

Through-space transmission of 19F-13C coupling via an intermediate bond. An experimental and theoretical study

ID Rae, A Staffa, AC Diz, CG Giribet, MCR de Azúa, RH Contreras

Journal article  |  1987  |  Australian Journal of Chemistry

In order to obtain a deeper insight into the title effect, several compounds with an F atom very close to a C-H of a nearby functi..

Borodin composer & chemist

GB Kauffman, ID Rae, YI Solov'ev, C Steinberg

Journal article  |  1987  |  Chemical & Engineering News

Hydride transfers during friedel-crafts reactions of 5, 5-Dimethyl-4, 5- dihydrofuran-2(3 H)-one

ID Rae, ML Woolcock

Journal article  |  1987  |  Australian Journal of Chemistry

5,5-Dimethyl-4,5-dihydrofuran-2(3H)-one (4,4-dimethylbutyrolactone) reacts with toluene and with p-xylene in the presence of anhyd..

Thermal Degradation of Polymers. II Synthesis and Characterization of a Compound which Models the Head-to-Head Linkage in Poly(methyl methacrylate)

GD Fallon, ML Felsbourg, KA Holland, ID Rae

Journal article  |  1987  |  Australian Journal of Chemistry

As models for a poly(methyl methacrylate ) chain which contains a head-to-head unit, the (�)- and meso -isomers of tetramethyl 2..

NMR-SPECTRA AND SOLUTION STRUCTURES OF SOME PIPERAZINE-2,5-DIONES - X-RAY CRYSTAL-STRUCTURE OF THREO-1-ACETYL-3-(ALPHA-BROMOBENZYL)-3-METHOXY-PIPERAZINE-2,5-DIONE

JA ELIX, GD FALLON, SM MARCUCCIO, ID RAE

Journal article  |  1986  |  Australian Journal of Chemistry

A polarization propagator analysis of through‐space spin‐spin coupling constants: 19F‐19F couplings

MCR De Azua, AC Diz, CG Giribet, RH Contreras, ID Rae

Journal article  |  1986  |  International Journal of Quantum Chemistry

Oxazolidines: prodrugs for the delivery of β-aminoalcohols through human skin from aqueous solution

JA Young-Harvey, ID Rae, IH Pitman

Journal article  |  1986  |  International Journal of Pharmaceutics

Transmission mechanisms of four-bond 19F19F coupling constants in fluoropropenes: A theoritical and experimental study

MA Natiello, RH Contreras, HO Gavarini, ID Rae

Journal article  |  1985  |  Chemical Physics

The stereochemistry of organometallic compounds. XXVII nucleophilic and electrophilic substitution reactions of conformationally restricted arenechromium compounds

W Roy Jackson, ID Rae, MG Wong

Journal article  |  1985  |  Australian Journal of Chemistry

The regioselectivity of reaction of tricarbonyl (1,1- dimethylindane )chromium with selected electrophiles and nucleophiles ..

Thermal degradation of polymers. I integrity of monomer derived from thermal degradation of poly(methy1 methacrylate) and poly(methacrylonitri1e)

AN Hodder, KA Holland, ID Rae

Journal article  |  1985  |  Australian Journal of Chemistry

A random copolymer of methyl methacrylate and its (D5)analogue has been used to show that thermal degradation of the polymer reg..

Relaxation processes in aromatic methyl groups. I 2-Chloro- and 2, 6-Dichloro-toluene

DJ Craik, RM Drew, I Kyratzis, ID Rae, JA Weigold

Journal article  |  1985  |  Australian Journal of Chemistry

Three series of selectively deuterated toluenes, 2-chlorotoluenes and 2,6-dichlorotoluenes have been synthesized, and their methyl..

Isolation of teratogenic alkaloids by reversed-phase high-performance liquid chromatography.

CA Browne, FR Sim, ID Rae, RF Keeler

Journal article  |  1984  |  Journal of Chromatography B: Biomedical Sciences and Applications

Reversed-phase high-performance liquid chromatography was used for both analytical and preparative separations of several steroida..

Fluorine magnetic resonance studies. VI: Fluorine-fluorine coupling over four bonds in a-fluoro- and α,α-difluoro-toluenes

ID Rae, DA Burgess, S Bombaci, ML Baron, ML Woolcock

Journal article  |  1984  |  Australian Journal of Chemistry

The 4J fluorine-fluorine coupling over four bonds involving an sp3 carbon and two sp2 carbons has been studied by using constraine..

The 13C N.M.R. Spectra of some arenetricarbonylchromium compounds, and their dicarbonyl triphenylphosphine, triphenyl phosphite and diphenylphosphinite analogues, including chelate compounds

W Roy Jackson, ID Rae, MG Wong

Journal article  |  1984  |  Australian Journal of Chemistry

A number of new arenetricarbonylchromium compounds have been synthesized in which the arene ring is substituted with a number of l..

Fluorine Magnetic Resonance Studies. VII Fluorine-Fluorine Coupling Over Five Bonds in l-Fluoro-2-(2′-fluorophenyl)ethanes

DA Burgess, MF Finn, D Jordan, ID Rae, BD Walters

Journal article  |  1984  |  Australian Journal of Chemistry

Spin-spin coupling between an aromatic fluorine and fluorines in an adjacent side chain (Ar-C-C-F), with J values in the range 2-5..

The dynamic stereochemistry of some dicarbonyl[phosphorus(III)](I,3-di-t- butyl-2-methoxyarene)chromium compounds. Evidence for restricted rotation about arene-substituent bonds, including an x-ray crystal structure of dicarbonyl(triphenylphosphine)(1,3-di-t-butyl-2-methoxybenzene)chromium

EM Campi, BMK Gatehouse, WR Jackson, ID Rae, MG Wong

Journal article  |  1984  |  J. Chem. Soc., Chem. Commun.

A CONFORMATIONAL STUDY OF THE TETRAPEPTIDE CH3CO-ALA-ASP-GLY-LYS-NHCH3 CORRESPONDING TO A BETA-BEND IN STAPHYLOCOCCAL NUCLEASE

DJ EVANS, ID RAE, E MINASIAN, G NEMETHY, HA SCHERAGA, SJ LEACH

Journal article  |  1983  |  Journal of Protein Chemistry

THERMAL DEGRADATION OF SELECTIVELY DEUTERATED POLY(METHYL METHACRYLATE).

AN Hodder, KA Holland, ID Rae

Journal article  |  1983  |  Journal of Polymer Science: Polymer Letters Edition

Synthetic approaches to mycorrhizin a and gilmicolin. II early introduction of a C3 side chain into a benzofuranol precursor

RFC Brown, GL Edwards, CM Jones, ID Rae, PYT Teo

Journal article  |  1983  |  Australian Journal of Chemistry

An attempt to modify the previously reported synthesis of the tricyclic system (1) of mycorrhizin A (2) and gilmicolin (3) by very..

Conformational analysis of the ergot alkaloids ergotamine and ergotaminine.

L Pierri, IH Pitman, ID Rae, DA Winkler, PR Andrews

Journal article  |  1982  |  Journal of Medicinal Chemistry

Conformational analyses by 1H NMR and potential-energy calculations are reported for the ergot alkaloids ergotamine and ergotamini..

Synthesis of the Cyclopropa[c]benzofuran System of Mycorrhizin A and of Gilmicolin from a Benzofuranol. Crystal Structure of a 5, 8-Methanocyclopropa[c]naphtho[2, 3-b]furan Derivative

RFC Brown, GD Fallon, BM Gatehouse, CM Jones, ID Rae

Journal article  |  1982  |  Australian Journal of Chemistry

The cyclopropa[c]benzofuran derivative (17), which contains the structural features of methyl ethers of mycorrhizin A and gilmicol..

Stereoelectronic control of the regioselectivity of both electrophilic and nucleophilic substitution of η6-(1,1-dimethylindane) tricarbonylchromium(0)

WR Jackson, ID Rae, MG Wong, MF Semmelhack, JN Garcia

Journal article  |  1982  |  J. Chem. Soc., Chem. Commun.

The Reaction of Piperazine-2, 5-dione with 2-Formylbenzoic Acid

ML Baron, ID Rae, PM Simmonds

Journal article  |  1982  |  Australian Journal of Chemistry

Reaction of piperazine-2,5-dione with 2-formylbenzoic acid in the presence of triethylamine gives three products: 1-(3'-oxo-1',3'-..

Ring Current Shielding and Molecular Motions in Piperazine-2, 5-diones

IJ Frigerio, ID Rae, MG Wong

Journal article  |  1982  |  Australian Journal of Chemistry

In 3-(phenylmethyl)piperazine-2,5-dione (cyclo(Phe-Gly)) the C6 methylene hydrogens are shielded by the aromatic ring which lies a..

Conformation and structure of the alkaloids ergotamine and ergotaminine

L Pierri, DA Winkler, ID Rae

Journal article  |  1981  |  Australian Journal of Pharmaceutical Sciences

CONFORMATION OF CYCLO(L-ALANYLGLYCYL-EPSILONAMINOCAPROYL), A CYCLIZED DIPEPTIDE MODEL FOR A BETA-BEND .2. SYNTHESIS, NUCLEAR MAGNETIC-RESONANCE, AND CIRCULAR-DICHROISM MEASUREMENTS

R DESLAURIERS, DJ EVANS, SJ LEACH, YC MEINWALD, E MINASIAN, G NEMETHY, ID RAE, RL SOMORJAI, ER STIMSON, JW VANNISPEN, RW WOODY, HA SCHERAGA

Journal article  |  1981  |  Macromolecules

Generation of spirodienones related to gilmicolin and mycorrhizin A

RFC Brown, BR Matthews, ID Rae

Journal article  |  1981  |  Tetrahedron Letters

Preparation of isobenzofuran-l(3h)-ones by decarbonylation of 1h-2-benzopyran-l, 3(4h)-diones

KJ Quinn, ID Rae

Journal article  |  1981  |  Australian Journal of Chemistry

3,3-Dimethyl-1H-2-benzopyran-1,3(4H)-dione (3,3-dimethylhomophthalic anhydride) is decarbonylated in the presence of aluminium chl..

CONFORMATIONAL CHARACTERISTICS OF THE N-ACETYL-N'-METHYLAMIDES OF THE 4 (LYS, TYR) DIPEPTIDES

ID RAE, SJ LEACH, E MINASIAN, JA SMITH, SS ZIMMERMAN, JA WEIGOLD, ZI HODES, G NEMETHY, RW WOODY, HA SCHERAGA

Journal article  |  1981  |  International Journal of Peptide and Protein Research

MINERALOCORTICOID ACTIVITY OF 21-DEOXYALDOSTERONE DERIVATIVES - STRUCTURE-FUNCTION STUDIES

KN WYNNE, ID RAE, DF OKEEFE, WR ADAM, P PEARCE, JR STOCKIGT, JW FUNDER

Journal article  |  1981  |  Journal of Steroid Biochemistry

Carbon-13 n.m.r. spectra of some 1-substituted azulenes

PR Wells, KG Penman, ID Rae

Journal article  |  1980  |  Australian Journal of Chemistry

The 13C n.m.r. spectra of 1-R-azulenes, where R = NO2, CN, COCH3, COCF3, Br, OMe, OCOPh and NH2, have been assigned by comparison ..

Mineralocorticoid activity of 21-deoxyaldosterone derivatives: Structure-function studies

KN Wynne, ID Rae, D O'Keefe

Journal article  |  1980  |  Proceedings of the Endocrine Society of Australia

The Crystal and Molecular Structure of (±)-(‘E, ’)-N-Acetylpiperidine-2-carboxylic Acid

ID Rae, CL Raston, AH White

Journal article  |  1980  |  Australian Journal of Chemistry

The crystal structure of N-acetylpiperidine-2-carboxylic acid has been determined by single-crystal X-ray diffraction methods at 2..

Fluorine magnetic resonance studies. V: Fluorine-fluorine coupling in 1, 4-difluorobenzenes

CA Kerr, JK Quinn, ID Rae

Journal article  |  1980  |  Australian Journal of Chemistry

A number of substituted 1,4-difluorobenzenes were examined by 19F n.m.r. spectroscopy and 5JFF was found to vary with the nature o..

H and 13C nuclear magnetic resonance spectra of some peptides with fibrinogen-like reactivity.

ID Rae, HA Scheraga

Journal article  |  1979  |  International Journal of Peptide and Protein Research

The 1H and 13C spectra of four peptides, L-Phe-Val-Arg-pNA, D-Phe-Val-Arg-pNA, L-Phe-Pip-Arg-pNA and D-Phe-Pip-Arg-pNA (pNA = p-ni..

Carbon-13 N.M.R. spectra of some amides and lactams and their thio and seleno analogues

ID Rae

Journal article  |  1979  |  Australian Journal of Chemistry

13C N.M.R. spectra were determined, and resonances were assigned, for 27 amides and lactams and their thio and seleno analogues.

CYCLIZED DIPEPTIDE MODEL FOR A BETA-BEND

R DESLAURIERS, SJ LEACH, FR MAXFIELD, E MINASIAN, JR MCQUIE, YC MEINWALD, G NEMETHY, MS POTTLE, ID RAE, HA SCHERAGA, ER STIMSON, JW VANNISPEN

Journal article  |  1979  |  Proceedings of the National Academy of Sciences

Shielding effects of the D-Phe aromatic ring in the 1H NMR spectrum of gramicidine S.

ID Rae, HA Scheraga

Journal article  |  1978  |  Biochemical and Biophysical Research Communications

Nuclear magnetic resonance study of fibrinogen-like peptides and their structure in dimethyl sulfoxide and water.

PH von Dreele, ID Rae, HA Scheraga

Journal article  |  1978  |  Biochemistry

The 1H nuclear magnetic resonance (NMR) spectra of four fibrinogen-like oligopeptides (H-Gly-Pro-Ala-NH2, H-Arg-Gly-Pro-Ala-NH2, H..

A study of methyl-substituted 2-arylbicyclo [2, 2, l]hept-2-yl cations

JM Coxon, PJ Steel, JM Coddington, ID Rae, AJ Jones

Journal article  |  1978  |  Australian Journal of Chemistry

The 13C and 1H N.M.R. spectra of a series of 2-aryl-1,7,7- trimethylbicyclo[2,2,1]hept-2-yl cations generated in strong acid at lo..

Aromatic amides. xi: 1, 3- Phenylenediamines and their diacyl derivatives

ID Rae

Journal article  |  1978  |  Australian Journal of Chemistry

In 4,6-disubstituted N,N'-(1,3-phenylene)bispivalamides, the ring hydrogen between the two amide groups is deshielded by both and ..

The stereochemistry of conjugate addition of lithium aluminium hydride to some norbornadiene esters. An unusual case of preferred endo attack.

WR Jackson, JW Norman, ID Rae

Journal article  |  1978  |  Tetrahedron Letters

Nitrones and oxaziridines. xx: Intramolecular nitrone 1, 3-dipolar cycloaddition by substituent interaction: Synthesis and reduction of some tetrahydropyrroloisoxazoles

DC Black, RF Crozier, ID Rae

Journal article  |  1978  |  Australian Journal of Chemistry

The reactions of C-benzoylnitrones with allylamine afford tetrahydro-5H-pyrrolo[3,4-c]isoxazoles resulting from imine formation an..

Some friedel-crafts reactions of γ-butyrolactone

CA Kerr, ID Rae

Journal article  |  1978  |  Australian Journal of Chemistry

Benzene reacts with γ-butyrolactone and aluminium chloride to give tetralone, but no detectable amount of 3-methylindan-1-one. p-D..

Nitrones and oxaziridines. XXI electronic substituent effects in nitrone cycloadditions to highly Polarized Alkenes

DSC Black, RF Crozier, ID Rae

Journal article  |  1978  |  Australian Journal of Chemistry

1,3-Dipolar cycloaddition reactions of nitrones-particularly N-(2'- pyridylmethylene)aniline N-oxide-with arylmethylene cyanoaceta..

A study of the reactions of 2-aryl-3, 3-dimethylbicyclo[2, 2, 1]heptan-2-ols with acid

JM Coxon, PM Pojer, PJ Steel, ID Rae, AJ Jones

Journal article  |  1978  |  Australian Journal of Chemistry

The 13C and 1H N.M.R. spectra of a series of 2-aryl-3,3- dimethylbicyclo[2,2,1]hept-2-yl cations generated in strong acid at low t..

The constitution of N-substituted 2- (Iminomethyl)benzenethiols (o-mercaptobenzaldimines)

MF Corrigan, ID Rae, BO West

Journal article  |  1978  |  Australian Journal of Chemistry

The constitution of a number of 2-(iminomethyl)benzenethiols and 2- (iminomethyl)-4-nitrobenzene-thiols has been studied by 1H N.M..

A study of cations generated from 1-Methyl- and 7, 7-Dimethyl-2-phenyIbicyclo[2, 2, l]heptan-2-oIs

RFC Brown, JM Coddington, JM Coxon, AJ Jones, ID Rae, PJ Steel

Journal article  |  1978  |  Australian Journal of Chemistry

Attempts to generate the 1-methyl-2-phenylbicyclo[2,2,1]hept-2-yl cation (6) by reaction of 1-methyl-exo-2-phenylbicyclo[2,2,1]hep..

Conversion of 2-nitrobenzonitrile into benzoic acid

AC Ellis, ID Rae

Journal article  |  1977  |  Journal of the Chemical Society, Chemical Communications

Nuclear Overhauser effects and the conformation of gramicidin S.

ID Rae, ER Stimson, HA Scheraga

Journal article  |  1977  |  Biochemical and Biophysical Research Communications

Carbon-13 Nuclear Magnetic Resonance Examination of Naphthalene Derivatives. Assignments and Analysis of Substituent Chemical Shifts

W Kitching, M Bullpitt, D Gartshore, W Adcock, TC Khor, D Doddrell, ID Rae

Journal article  |  1977  |  The Journal of Organic Chemistry

Reassignment of the 13C N.M.R. parameters of the 2-Phenylbicyclo[2,2,1]-hept-2-yl cation

JM Coxon, PJ Steel, JM Coddington, ID Rae, AJ Jones

Journal article  |  1977  |  Australian Journal of Chemistry

Three of the seven carbon resonances, namely C5, C6 and C7, in the 13C N.M.R. spectrum of the 2-phenylbicyclo[2,2,1]hept-2-yl cati..

The hydrogenolysis of 1,8-cineole

HM Hügel, WR Roy Jackson, CD Kachel, ID Rae

Journal article  |  1977  |  Australian Journal of Chemistry

Reaction of 1,8-cineole with hydrogen over supported platinum and palladium catalysts gives mixtures of cis- and trans-p-menthanes..

Fluorine magnetic resonance studies. IV* α,2-Difluoro- and α,α,2-Trifluoro-toluenes

DA Burgess, ID Rae

Journal article  |  1977  |  Australian Journal of Chemistry

Fluorine-fluorine coupling over four bonds has been observed in the 19F N.M.R. spectra of three α,2-difluorotoluenes and three α,α..

Oxidation of alkyl groups accompanying the Zinin reduction of nitroarenes

DA Burgess, ID Rae

Journal article  |  1977  |  Australian Journal of Chemistry

p-Aminobenzaldehydes have been prepared from several nitroxylenes and trimethylnitrobenzenes by reaction with aqueous alcoholic so..

Fluorine magnetic resonance studies. III* Fluorine-fluorine coupling over six and seven bonds in fluorostyrenes

DA Burgess, ID Rae, JD Snell

Journal article  |  1977  |  Australian Journal of Chemistry

The 19F nuclear magnetic resonance spectra of β,β-difluorostyrenes and 1-difluoromethyleneindans bearing fluorine substituents in ..

The stereochemistry of organometallic compounds. XIV. trans-Effects in the 13C N.M.R. spectra of Dicarbonyltriphenyl-phosphine- and arsine-(arene)chromium compounds

W Roy Jackson, CF Pincombe, ID Rae, D Rash, B Wilkinson

Journal article  |  1976  |  Australian Journal of Chemistry

The 13C chemical shifts of some triphenyl-phosphine and -arsine dicarbonyl(arene)chromiums are reported. The shifts are discussed ..

Flash thermolysis of thioformanilides

RFC Brown, JM Coddington, ID Rae, GJ Wright

Journal article  |  1976  |  Australian Journal of Chemistry

Flash thermolysis of several thioformanilides at approximately 700� gives good yields of aromatic nitriles.

Fluorine magnetic resonance studies. II* Long-range fluorine-fluorine coupling in 2, β, β-Trifluorostyrenes and related compounds

DA Burgess, ID Rae, LK Smith, JD Snell

Journal article  |  1976  |  Australian Journal of Chemistry

Five β,β-difluorostyrenes and a 1-difluoromethyleneindan bearing a fluorine substituent on the aromatic ring ortho to the side cha..

Lanthanide shifts in the 1H N.M.R. spectra of thioamides, selenoamides and 1,2-dithioles

ID Rae

Journal article  |  1975  |  Australian Journal of Chemistry

The effects of lanthanide shift reagents on the spectra of thioamides and related amides and selenoamides are reported, and compar..

Preparation of 2,2,7-trimethyloct-6-en-3-one from cineole

CD Kachel, ID Rae, AM Redwood

Journal article  |  1975  |  Australian Journal of Chemistry

2,2,7-Trimethyloct-6-en-3-one is formed by decomposition of two tetrahydropyran derivatives derived from cineole. A rational synth..

The lanthanide-shifted N.M.R. spectra of some cyclopentadienone-cobalt complexes

RS Dickson, SH Johnson, ID Rae

Journal article  |  1975  |  Australian Journal of Chemistry

The effect of the lanthanide shift reagents, Eu(fod)3 and Pr(fod)3, on the nuclear magnetic resonance spectra of some (η4-cyclopen..

3,4,5,6,7,8-Hexahydronaphthalen-1(2H)-ones. Synthesis and photoaddition to (Z)-1,2-Dichloroethylene

ID Rae, BN Umbrasas

Journal article  |  1975  |  Australian Journal of Chemistry

Several cyclohexanones have been converted, via cyclohexylidenebutyric acids, into 3,4,5,6,7,8-hexa-hydronaphthalen-1(2H)-ones in ..

Carbonium ion rearanggement of the 2-phenylbornyl skeleton

JM Coxon, AJ Jones, CP Beeman, MU Hasan, ID Rae

Journal article  |  1975  |  Tetrahedron Letters

The stereochemistry of organometallic compounds. XIII: The 13C N.M.R. spectra of some tricarbonyl(arene)chromium compounds

W Roy Jackson, CF Pincombe, ID Rae, S Thapebinkarn

Journal article  |  1975  |  Australian Journal of Chemistry

The 13C n.m.r, spectra of a series of tricarbonyl(arene)chromiums have been determined. The spectra are interpreted in terms of el..

π-Allylic palladium schiff base complexes

ID Rae, BE Reichert, BO West

Journal article  |  1974  |  Journal of Organometallic Chemistry

Aromatic amides: IX. Temperature effects on the N.M.R. spectra of substituted acetanilides

ID Rae

Journal article  |  1974  |  Australian Journal of Chemistry

N.m.r. spectra have been measured for several anilides in dimethyl sulphoxide solution for temperatures in the range 40-140�. The ..

An N.M.R. study of some esters and lactones derived from cineolic anhydride

ID Rae, AM Redwood

Journal article  |  1974  |  Australian Journal of Chemistry

Cineolic anhydride is attacked by nucleophiles exclusively at its more exposed carbonyl group. The dimethyl ester of cineolic acid..

Aromatic amides: X. Anisotropic shielding by protonated amide and thioamide groups

ID Rae

Journal article  |  1974  |  Australian Journal of Chemistry

N.m.r. spectra have been recorded for solutions of N-aryl amides and thioamides in trifluoroacetic acid. Anisotropic deshielding b..

Aromatic amides. VIII. Z, E isomer ratios and stereochemistry about aryl-nitrogen bonds in N-aryl amides and thioamides

DL Bate, ID Rae

Journal article  |  1974  |  Australian Journal of Chemistry

For 4?-substituted 2?,6?-diethylacetanilides, the Z/E isomer ratio depends on the nature of the 4?- substituent, the Z isomer bein..

Haplophytine. A Novel Type of Indole Alkaloid

P Yates, FN MacLachlan, ID Rae, M Rosenberger, AG Szabo, CR Willis, MP Cava, M Behforouz, MV Lakshmikantham, W Zeiger

Journal article  |  1973  |  Journal of the American Chemical Society

Formation of arylacetic acids, arylacetamides, and aryldihydropyrroles from aromatic aldehydes

L Breen, FW Eastwood, T Ockman, ID Rae, AM Redwood

Journal article  |  1973  |  Australian Journal of Chemistry

Furfuraldehyde, 4-hydroxybenzaldehyde, and 4-hydroxy-3-methoxybenzalde- hyde were converted into 2-furylacetic, 4-hydroxyphenylace..

The reaction of ortho-dinitrobenzenes with sodium borohydride

KJ Bird, ID Rae, AM White

Journal article  |  1973  |  Australian Journal of Chemistry

The reaction of o-dinitrobenzene with sodium borohydride in aqueous dimethyl sulphoxide at room temperature gives nitrobenzene and..

Fluorine magnetic resonance studies: I. Para-substituted β,β-difluorostyrenes

ID Rae, LK Smith

Journal article  |  1972  |  Australian Journal of Chemistry

A series of seven para-substituted β,β-difluorostyrenes has been prepared and their proton and fluorine magnetic resonance spectra..

Tetronic acid derivatives: Synthesis of an indolone-spiro-hydroxytetronimide

RG Amiet, FW Eastwood, ID Rae

Journal article  |  1972  |  Australian Journal of Chemistry

The synthesis of l-methylindol-2(3H)-one-3-spiro-2'-3',4'-dihydroxy5'-imino-2',5'-dihydrofuran (4; R1 = R2 H) is described. The co..

Aromatic amides: VII. Steric hindrance to hydrogen bonding in ortho-substituted acetanilides

BD Andrews, AJ Poynton, ID Rae

Journal article  |  1972  |  Australian Journal of Chemistry

A series of 2-substituted 3,5-dimethylanilines and their N-acetyl derivatives have been synthesized, and their proton magnetic res..

Species existing in solutions of Naphthalene-1, 4, 5, 8-tetracarboxylic acid

ID Rae

Journal article  |  1972  |  Australian Journal of Chemistry

The effects of electronic buttressing on the conformations of some ortho-disubstituted benzenes

RI Herrmann, ID Rae

Journal article  |  1972  |  Australian Journal of Chemistry

When one of a pair of substituents ortho to each other on a benzene ring is conjugated with an appropriate para substituent, it is..

Addition of a highly oxygenated side-chain to an indole derivative

RG Amiet, FW Eastwood, ID Rae

Journal article  |  1971  |  Journal of the Chemical Society D: Chemical Communications

Synthesis of 2-benzamido-2-mercaptopropanoic acid

PM Pojer, ID Rae

Journal article  |  1971  |  Tetrahedron Letters

Reaction of 2-(4'-thiazolyl)benzimidazole (thiabendazole) with alkyl halides

JA Maynard, ID Rae, D Rash, JM Swan

Journal article  |  1971  |  Australian Journal of Chemistry

2-(4?-Thiazolyl)benzimidazole (thiabendazole) is alkylated at a benzimidazole nitrogen by reaction with sodium hydride and an alky..

Preparation and reactions of 4-acetylthio-4-methy1-2-phenyl-2-thiazolin-5-one

ID Rae, BN Umbrasas

Journal article  |  1971  |  Australian Journal of Chemistry

Aromatic amides. VI. Proton magnetic resonance spectra of some 2-substituted 1, 3-phenylenediamines and their N, N’-diacyl derivatives

BD Andrews, ID Rae

Journal article  |  1971  |  Australian Journal of Chemistry

A number of 2-substituted 1,3-phenylenediamines and their N-acyl and N,N?-diacyl derivatives have been prepared and the proton mag..

Reaction of 2-benzamido-2-benzylthiopropanoic acid with N-chlorosuccinimide

PM Pojer, ID Rae

Journal article  |  1971  |  Tetrahedron Letters

Aromatic amides: V. Intramolecular hydrogen bonding in ortho-substituted anilides

JM Appleton, BD Andrews, ID Rae, BE Reichert

Journal article  |  1970  |  Australian Journal of Chemistry

The proton magnetic resonance spectra of deuterochloroform solutions of a number of ortho-substituted anilines and their S-acyl de..

Reactions of methylamine and aniline with methyl pyruvate

PM Pojer, ID Rae

Journal article  |  1970  |  Australian Journal of Chemistry

Intramolecular hydrogen bonding in 2′-substituted anilides

BD Andrews, ID Rae, BE Reichert

Journal article  |  1969  |  Tetrahedron Letters

Haplophytine

ID Rae, M Rosenberger, AG Szabo, CR Willis, P Yates, DE Zacharias, GA Jeffrey, B Douglas, JL Kirkpatrick, JA Weisbach

Journal article  |  1967  |  Journal of the American Chemical Society

A Solvent Effect on the Conformation of Aromatic Nitro Groups

ID Rae

Journal article  |  1967  |  Australian Journal of Chemistry

The differences between proton mangetic resonance spectra of aromatic nitro compounds in deuterochloroform and dimethyl sulphoxide..

Solvent Effects on the Conformations of Ortho-Nitroanilines

ID Rae

Journal article  |  1967  |  Australian Journal of Chemistry

Proton magnetic resonance spectroscopy has been used to examine the conformations of a number of ortho-nitroanilines in solution. ..

Solvent effects on hydrogen bonding in ortho-nitroanilines

ID Rae

Journal article  |  1966  |  Chemical Communications (London)

Spin-Spin Coupling in the System H-C-N-H. I. Weakly Basic Secondary Amines

ID Rae

Journal article  |  1966  |  Australian Journal of Chemistry

Proton-proton spin-spin coupling in the system H-C-N-H has been observed in a series of N-methylanilines. At 25� in deuterochlorof..

Correlation of N.M.R. Chemical Shifts of N-Methyl Protons of Substituted Dimethylanilines with Hammett Substituent Constants

ID Rae, LK Dyall

Journal article  |  1966  |  Australian Journal of Chemistry

The proton magnetic resonance chemical shifts of N-methyl protons in para-substituted NN-dimethylanilines have been correlated wit..

Synthetic Studies in the 1, 2-Dithiole Series. IV. The Methylation of 4-Benzamido-1, 2-Dithiole-3-Thione

RFC Brown, ID Rae, JS Shannon, S Sternhell, JM Swan

Journal article  |  1966  |  Australian Journal of Chemistry

The product of methylation of 4-benzamido-1,2-dithiole-3-thione has been shown to be methyl 5-methylthio-2-phenyloxazole-4-carbodi..

Spin-Spin coupling in the system H-C-N-H. II. Variation of coupling constant with electronegativity of the N-substituent in N-substituted benzylamines

ID Rae

Journal article  |  1966  |  Australian Journal of Chemistry

Synthetic Studies in the 1, 2-dithiole Series. III. Attempts to Convert Dithioles into Pyrrolodithioles

RFC Brown, ID Rae

Journal article  |  1965  |  Australian Journal of Chemistry

��� Some unsuccessful attempts to convert 4-acylamino-1,2-dithiole derivatives into pyrrolodithioles are described, and the failur..

2-alkylidene-1-phenyloxazolidine-4, 5 diones

KR Markham, ID Rae

Journal article  |  1965  |  Australian Journal of Chemistry

Synthetic Studies in the 1, 2-Dithiole Series. II. Routes to 4-Methylamino-1, 2-dIthiole-3-Thione

RFC Brown, ID Rae, S Sternhell

Journal article  |  1965  |  Australian Journal of Chemistry

4-Amino-1,2-dithiol-3-one has been converted via methylation of its N-tosyl derivative into the 4-methylamino-3-thione (Vb). Methy..

A Proton Magnetic Resonance Study of Molecular Overcrowding in N-Alkyl-O-Nitroanilines

ID Rae

Journal article  |  1965  |  Australian Journal of Chemistry

The chemical shift of an aromatic proton adjacent to a nitro group is sensitive to the degree of coplanarity between the nitro gro..

Synthetic studies in the 1, 2-dithiole series. I. Derivatives of 4-amino-1, 2-dithiol-3-one

RFC Brown, ID Rae

Journal article  |  1964  |  Australian Journal of Chemistry

Hippuric acid has been converted into 4-benzamido-1,2-dithiol-3-one (16% yield) by the successive action of ethyl orthoformate in ..

Isoflavonoids. I. Some new constituents of pterocarpus indicus heartwood

RG Cooke, ID Rae

Journal article  |  1964  |  Australian Journal of Chemistry

A new examination of the heartwood of Pterocarpus indicus has revealed the presence of formononetin, isoliquiritigenin, (-)-p-hydr..