Richard Robson

Tuning Charge-State Localization in a Semiconductive Iron(III)-Chloranilate Framework Magnet Using a Redox-Active Cation

Martin P van Koeverden, Brendan F Abrahams, Deanna M D'Alessandro, Patrick W Doheny, Carol Hua, Timothy A Hudson, Guy NL Jameson, Keith S Murray, Wasinee Phonsri, Richard Robson, Ashley L Sutton

Journal article  |  2020  |  CHEMISTRY OF MATERIALS

The elucidation of mechanisms to modulate the properties of multifunctional electroactive, conductive, and magnetic porous materia..

A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4 4] metallocycles

Ashley L Sutton, Brendan F Abrahams, Timothy A Hudson, Richard Robson

Journal article  |  2020  |  NEW JOURNAL OF CHEMISTRY

Redox-active ligands are of interest for their ability to link metal centres and generate electroactive materials. We report the s..

Semi-conducting mixed-valent X(4)TCNQ(I-/II-)(X = H, F) charge-transfer complexes with C6H2(NH2)(4)

Ashley L Sutton, Brendan F Abrahams, Deanna M D'Alessandro, Lars Goerigk, Timothy A Hudson, Richard Robson, Pavel M Usov

Journal article  |  2020  |  JOURNAL OF MATERIALS CHEMISTRY C

We report further characterisation on the previously described [C6H2(NH2)4][TCNQ] charge-transfer (CT) complex. An in-depth analys..

The Effect of Sterically Active Ligand Substituents on Gas Adsorption within a Family of 3D Zn-Based Coordination Polymers

Brendan F Abrahams, Ravichandar Babarao, A David Dharma, Jessica L Holmes, Timothy A Hudson, Helen E Maynard-Casely, Forbes McGain, Richard Robson, Keith F White

Journal article  |  2020  |  Inorganic Chemistry

An investigation of the adsorption properties of two structurally related, 3D coordination polymers of composition Zn(2-Mehba) and..

A Semiconducting Cationic Square-Grid Network with Fe-III Centers Displaying Unusual Dynamic Behavior

Timothy A Hudson, Ashley L Sutton, Brendan F Abrahams, Deanna M D'Alessandro, Casey G Davies, Lars Goerigk, Guy NL Jameson, Boujemaa Moubaraki, Keith S Murray, Richard Robson, Pavel M Usov, Guochun Yang

Journal article  |  2020  |  EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The synthesis, structure and properties of a 2D FeIII network material of composition [Fe(O-bipy)2Cl](TCNQ)2 (O-bipy = 4,4'-bipyri..

Effects of Mixed Valency in an Fe-Based Framework: Coexistence of Slow Magnetic Relaxation, Semiconductivity, and Redox Activity

Ryuichi Murase, Christopher J Commons, Timothy A Hudson, Guy NL Jameson, Chris D Ling, Keith S Murray, Wasinee Phonsri, Richard Robson, Qingbo Xia, Brendan F Abrahams, Deanna M D'Alessandro

Journal article  |  2020  |  INORGANIC CHEMISTRY

A 2-D coordination framework, (NEt4)2[Fe2(fan)3] (1·5(acetone); H2fan = 3,6-difluoro-2,5-dihydroxy-1,4-benzoquinone), was synthesi..

Square Grid Metal-Chloranilate Networks as Robust Host Systems for Guest Sorption

Christopher J Kingsbury, Brendan F Abrahams, Josie E Auckett, Hubert Chevreau, A David Dharma, Samuel Duyker, Qilin He, Carol Hua, Timothy A Hudson, Keith S Murray, Wasinee Phonsri, Vanessa K Peterson, Richard Robson, Keith F White

Journal article  |  2019  |  CHEMISTRY-A EUROPEAN JOURNAL

Reaction of the chloranilate dianion with Y(NO3 )3 in the presence of Et4 N+ in the appropriate proportions results in the formati..

Self-assembly of a Si-based cage by the formation of 24 equivalent covalent bonds

Jessica L Holmes, Brendan F Abrahams, Anna Ahveninen, Berin A Boughton, Timothy A Hudson, Richard Robson, Dinaiz Thinagaran

Journal article  |  2018  |  CHEMICAL COMMUNICATIONS

A robust, nano-sized covalent cage, of composition, [(PhSi)6(ctc)4]6- (H6ctc = cyclotricatechylene) has been prepared in a simple ..

Interligand Charge-Transfer Interactions in Electroactive Coordination Frameworks Based on N,N'-Dicyanoquinonediimine (DCNQI)

Robert W Elliott, Pavel M Usov, Brendan F Abrahams, Bun Chan, Richard Robson, Deanna M D'Alessandro

Journal article  |  2018  |  INORGANIC CHEMISTRY

Coordination frameworks containing DCNQI2- (DCNQI = N, N'-dicyanoquinonediimine ligand) are produced by deprotonation of DCNQIH2 i..

X(4)TCNQ(2-) dianions: versatile building blocks for supramolecular systems

Brendan F Abrahams, Robert W Elliott, Timothy A Hudson, Richard Robson, Ashley L Sutton

Journal article  |  2018  |  CRYSTENGCOMM

In 2008 a new approach to generating tetracyanoquinodimethane (TCNQ)-based materials was described which involved the use of the d..