Colette Boskovic

Modulating the electronic properties of divalent lanthanoid complexes with subtle ligand tuning

Moya AA Hay, Robert WW Gable, Colette Boskovic

Journal article  |  2023  |  DALTON TRANSACTIONS

Five new compounds of formula [LnII(Mentpa)2](BPh4)2 (Ln = Eu, n = 0 (1-Eu), n = 2 (2-Eu) and n = 3 (3-Eu); Ln = Yb, n = 0 (1-Yb) ..

Inelastic Neutron Scattering Measurement of the Ground State Tunneling Gap in Tb and Ho Analogues of a Dy Field-Induced Single-Molecule Magnet

Alessandro Soncini, Richard A Mole, Colette Boskovic, Aiden M Atkin, Marcus J Giansiracusa, Simone Calvello, Elodie Rousset, Robert W Gable, Wasinee Phonsri, Keith S Murray, James K Howard

Journal article  |  2023  |  INORGANIC CHEMISTRY

Recent advances in single-molecule magnet (SMM) research have placed great value on interpretation of inelastic neutron scattering..

Direct observation of magnetoelastic coupling in a molecular spin qubit: new insights from crystal field neutron scattering data

Maja A Dunstan, Marcus J Giansiracusa, Michele Vonci, Simone Calvello, Dehong Yu, Alessandro Soncini, Colette Boskovic, Richard A Mole

Journal article  |  2023  |  Chemical Science

Magnetoelastic coupling has been investigated using inelastic neutron scattering. This has allowed the spin–phonon coupling of the..

Modulation of Charge Distribution in Cobalt-?-Diimine Complexes toward Valence Tautomerism

Moya A Hay, Jett T Janetzki, Varshini J Kumar, Robert W Gable, Rodolphe Clerac, Alyona A Starikova, Paul J Low, Colette Boskovic

Journal article  |  2022  |  INORGANIC CHEMISTRY

Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing a range of molecular materials for sensing,..

Elucidation of LMCT Excited States for Lanthanoid Complexes: A Theoretical and Solid-State Experimental Framework

Elodie Rousset, Matteo Piccardo, Robert W Gable, Massimiliano Massi, Lorenzo Sorace, Alessandro Soncini, Colette Boskovic

Journal article  |  2022  |  INORGANIC CHEMISTRY

Photophysical and magnetic properties arising from both ground and excited states of lanthanoid ions are relevant for numerous app..

Modulation of Slow Magnetic Relaxation in Gd(III)-Tetrahalosemiquinonate Complexes

Maja A Dunstan, Dominic S Brown, Lorenzo Sorace, Richard A Mole, Colette Boskovic

Journal article  |  2022  |  CHEMISTRY-AN ASIAN JOURNAL

Incorporating lanthanoid(III)-radical magnetic exchange coupling is a possible route to improving the performance of lanthanoid (L..

Magnetic properties and neutron spectroscopy of lanthanoid-{tetrabromocatecholate/18-crown-6} single-molecule magnets

Maja A Dunstan, Marina Cagnes, Wasinee Phonsri, Keith S Murray, Richard A Mole, Colette Boskovic

Journal article  |  2022  |  AUSTRALIAN JOURNAL OF CHEMISTRY

Lanthanoid single-molecule magnets (Ln-SMMs) exhibit slow magnetic relaxation at low temperatures. This arises from an energy barr..

Rich redox-activity and solvatochromism in a family of heteroleptic cobalt complexes

Vincent L Nadurata, Moya A Hay, Jett T Janetzki, Gemma K Gransbury, Colette Boskovic

Journal article  |  2021  |  DALTON TRANSACTIONS

The combination of redox-active metals with redox-active ligands can lead to interesting charge transfer behaviours, including val..

Valence Tautomerism in D‐Block Complexes

Gemma K Gransbury, Colette Boskovic

Book Chapter  |  2021

A Convenient DFT-Based Strategy for Predicting Transition Temperatures of Valence Tautomeric Molecular Switches

Jett T Janetzki, F Zahra M Zahir, Robert W Gable, Wasinee Phonsri, Keith S Murray, Lars Goerigk, Colette Boskovic

Journal article  |  2021  |  INORGANIC CHEMISTRY

The ability to identify promising candidate switchable molecules computationally, prior to synthesis, represents a considerable ad..