Getting the Drift - New Frontiers in Ion Spectroscopy

Photo and Collision Induced Isomerization of a Cyclic Retinal Derivative: An Ion Mobility Study

NJA Coughlan, MS Scholz, CS Hansen, AJ Trevitt, BD Adamson, EJ Bieske

2016-09-01

A cationic degradation product, formed in solution from retinal Schiff base (RSB), is examined in the gas phase using ion mobility..

Photoisomerization of β-ionone protonated Schiff base in the gas phase

NJA Coughlan, CM Wallace, BD Adamson, EJ Bieske

2016-08-25

The photoisomerization of β-ionone protonated Schiff base (BIPSB) is investigated in the gas phase by irradiating mobility-selecte..

Ab Initio Characterization of the Electrostatic Complexes Formed by H2 Molecule and Cr , Mn , Cu , and Zn Cations

DG Artiukhin, EJ Bieske, AA Buchachenko

2016-07-14

Equilibrium structures, dissociation energies, and rovibrational energy levels of the electrostatic complexes formed by molecular ..

Blue to near-IR energy transfer cascade within a dye-doped polymer matrix, mediated by a photochromic molecular switch

V Dryza, TA Smith, EJ Bieske

2016-01-01

The spectroscopic properties of a poly(methyl methacrylate) matrix doped with a coumarin dye, a cyanine dye, and a photochromic sp..

Electronic spectrum of the propargyl cation (H2C3H ) tagged with Ne and N2

KJ Catani, JA Sanelli, V Dryza, N Gilka, PR Taylor, EJ Bieske

2015-11-14

The ù A<inf>1</inf> larr; X¹ A<inf>1</inf> band system of the propargyl cation (H<inf>2</inf>C<inf>3</inf>H..

Gas-phase electronic spectrum of the indole radical cation

N Chalyavi, KJ Catani, JA Sanelli, V Dryza, EJ Bieske

2015-08-18

The visible and near-UV electronic spectrum of the indole radical cation is measured in the gas phase by photodissociation of indo..

Retinal shows its true colours: Photoisomerization action spectra of mobility-selected isomers of the retinal protonated Schiff base

NJA Coughlan, BD Adamson, L Gamon, K Catani, EJ Bieske

2015-08-05

Retinal is one of Nature's most important and widespread chromophores, exhibiting remarkable versatility in its function and spect..

Photoisomerization action spectroscopy: flicking the protonated merocyanine-spiropyran switch in the gas phase

PB Markworth, BD Adamson, NJA Coughlan, L Goerigk, EJ Bieske

2015-05-26

Laser spectroscopy and ion mobility spectrometry are combined to provide structural and photochemical information on photoisomeriz..

Ultraviolet photodissociation action spectroscopy of the N-pyridinium cation

CS Hansen, SJ Blanksby, N Chalyavi, EJ Bieske, JR Reimers, AJ Trevitt

2015-01-01

The S<inf>1</inf>←S<inf>0</inf> electronic transition of the N-pyridinium ion (C<inf>5</inf>H<inf>5</inf>NH⁺) is invest..

An ion mobility mass spectrometer for investigating photoisomerization and photodissociation of molecular ions

BD Adamson, NJA Coughlan, PB Markworth, RE Continetti, EJ Bieske

2014-12-01

An ion mobility mass spectrometry apparatus for investigating the photoisomerization and photodissociation of electrosprayed molec..

Photoisomerization action spectrum of retinal protonated Schiff base in the gas phase

NJA Coughlan, KJ Catani, BD Adamson, U Wille, EJ Bieske

2014-04-28

The photophysical behaviour of the isolated retinal protonated n-butylamine Schiff base (RPSB) is investigated in the gas phase us..

Ion mobility unlocks the photofragmentation mechanism of Retinal protonated Schiff base

NJA Coughlan, BD Adamson, KJ Catani, U Wille, EJ Bieske

2014-01-01

Retinal protonated Schiff base (RPSB) is a key molecular component of biological photoreceptors and bacterial photosynthetic struc..

Photoisomerization action spectroscopy of the carbocyanine dye DTC in the gas phase

BD Adamson, NJA Coughlan, G Da Silva, EJ Bieske

2013-12-19

Molecular photoisomerization plays a crucial role in diverse biological and technological contexts. Here, we combine ion mobility ..

Photophysics and aggregation effects of a triphenylamine-based dye sensitizer on metal-oxide nanoparticles suspended in an ion trap

V Dryza, JL Nguyen, TH Kwon, WWH Wong, AB Holmes, EJ Bieske

2013-12-14

The photophysical behaviour of a triphenylamine-based organic dye sensitizer (Carbz-PAHTDTT) attached to alumina and titania nanop..

Non-covalent interactions between metal cations and molecular hydrogen: Spectroscopic studies of M -H2 complexes

V Dryza, EJ Bieske

2013-12-01

We describe recent infrared spectroscopic investigations of charged complexes consisting of a hydrogen or deuterium molecule attac..

Electronic spectroscopy of the 1,3-cyclopentadiene cation (C 5H6 )

N Chalyavi, JA Sanelli, V Dryza, EJ Bieske

2013-11-07

The gas-phase electronic spectrum of the 1,3-cyclopentadiene radical cation (C<inf>5</inf>H<inf>6</inf>⁺) has been inve..

Changing the shape of molecular ions: Photoisomerization action spectroscopy in the gas phase

BD Adamson, NJA Coughlan, RE Continetti, EJ Bieske

2013-06-28

A new approach for studying the photoisomerization of molecular ions in the gas phase is described. Packets of molecular ions are ..

Gas-phase electronic spectroscopy of the indene cation (C9H 8 )

N Chalyavi, V Dryza, JA Sanelli, EJ Bieske

2013-06-14

The electronic spectrum of the indene radical cation has been investigated through resonance-enhanced photodissociation of the wea..

Electronic absorptions of the benzylium cation

V Dryza, N Chalyavi, JA Sanelli, EJ Bieske

2012-11-28

The electronic transitions of the benzylium cation (Bz⁺) are investigated over the 250-550nm range by monitoring the ph..

Attaching molecular hydrogen to metal cations: Perspectives from gas-phase infrared spectroscopy

V Dryza, BLJ Poad, EJ Bieske

2012-11-21

In this perspective article we describe recent infrared spectroscopic investigations of mass-selected M ⁺-H <inf>2</inf..

Properties of the B -H 2 and B -D 2 complexes: A theoretical and spectroscopic study

BLJ Poad, V Dryza, AA Buchachenko, J Kos, EJ Bieske

2012-09-28

The rotationally resolved infrared spectrum of the B-D <inf>2</inf> ion-neutral complex is recorded in the D-D stretch vibration r..