Structures and Properties of Beta-Silyl and Beta-Chalcogenyl-Substituted Carbenium Ions

Application of the variable oxygen probe to determine the π-electron donor ability of the alkyne group

BL Harris, JM White

2014-01-01

Eight ester and ether derivatives of propargyl alcohol with varying electron demand were structurally characterised using low temp..

Structural investigations into the β-effect of pentavalent silicon

M Spiniello, JM White

2008-03-10

Ester and ether derivatives of 2-[(8-dimethylaminonaphthalen-1-yl) dimethylsilanyl]ethanol (10a) were prepared as part of a prelim..

Solution and solid-state structure of 2- And 4-bis(trimethylsilyl) methylpyridinium cations

K Hassall, CH Schiesser, JM White

2007-06-18

N-Methylation of the 2- and 4-bis(trimethylsilyl)methyl pyridines 7 and 9 gives the ions 5 and 6 and results in a significant decr..

Carbon-silicon hyperconjugation and strain-enhanced hyperconjugation: Structures of N-methyl 2- And 4-tert-butyldimethylsilylmethyl pyridinium cations

K Hassall, S Lobachevsky, CH Schiesser, JM White

2007-03-12

NBO analysis of the interaction of trialkylsilylmethyl substituents with the electron-deficient pyridinium cation suggests that hy..