Medium-Ring Effects on the Endo/Exo Selectivity of the Organocatalytic Intramolecular Diels-Alder Reaction
Joel F Hooper, Natalie C James, Esra Bozkurt, Viktorya Aviyente, Jonathan M White, Mareike C Holland, Ryan Gilmour, Andrew B Holmes, KN Houk
The Journal of Organic Chemistry | AMER CHEMICAL SOC | Published : 2015
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Awarded by Australian Research Council
Awarded by National Institutes of Health
Awarded by NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES
We thank the Australian government for an Australian Postgraduate Award (JFH) and the Australian Research Council for the award of a Discovery Project (DP0451189). We are grateful to the Gates Millennium Scholarship Program (NCJ), the National Institute of General Medical Sciences, and the National Institutes of Health (GM 36700 K.N.H.) for support of this work. Computations were performed using the Extreme Science and Engineering Discovery Environment (XSEDE) resources supported by the NSF (OCI-1053575) and the UCLA Institute for Digital Research and Education (IDRE)Hoffman2 cluster. We thank the German Academic Exchange Service (DAAD) for generous financial support (postdoctoral fellowship to M.C.H.). We thank Dr. Jonathan Burton for his interest in this work. Crystallographic data have been deposited with the Cambridge Crystallographic Data Centre under CCDC Nos. 1047892-1047894.