Nonlinear single-electron tunneling through individually coated colloid particles at room temperature

Abstract

Single-electron tunneling (SET) has been observed with nanometer coated colloid gold particles at room temperature. We have made the smallest (3-nm) thiol- and silicon dioxide (Formula presented)-coated gold particles, from which we obtained SET signals using a scanning tunneling microscope (STM). STM images reveal individual particles supported by an atomically flat metal surface. The STM tip is used to obtain SET signals from the individual particles, whose shapes have been characterized. The current-voltage curves of the particles exhibit well-defined Coulomb staircases that resemble those obtained at 4.2 K, indicating a strong Coulomb repulsive interaction at room temperature. The clear ..