Stereoelectronic effects of the group 4 metal substituents in organic chemistry

Abstract

This chapter contains sections titled: Introduction The donor ability of the C‐MR3 (M = Si, Ge, Sn, Pb) bond Interaction of C‐MR3 bonds with acceptor orbitals at the β position Interaction of C‐MR3 bonds with acceptor orbitals at the γ position Interaction of C‐MR3 bonds with acceptor orbitals at the δ position Interaction of C‐MR3 bonds with remote electron‐deficient orbitals Interaction of C‐MR3 bonds with π systems Interaction of C‐MR3 bonds with electron rich orbitals at the β position Comment: Interaction of group 4 metal substituents with singly occupied orbitals Introduction The donor ability of the C‐MR3 (M = Si, Ge, Sn, Pb) bond Interaction of C‐MR3 bonds with acceptor orbitals at t..