Activity–composition relations for the calculation of partial melting equilibria in metabasic rocks

Abstract

A set of thermodynamic models is presented that, for the first time, allows partial melting equilibria to be calculated for metabasic rocks. The models consist of new activity–composition relations combined with end-member thermodynamic properties from the Holland & Powell dataset, version 6. They allow for forward modelling in the system Na (Formula presented.) O–CaO–K (Formula presented.) O–FeO–MgO–Al (Formula presented.) O (Formula presented.) –SiO (Formula presented.) –H (Formula presented.) O–TiO (Formula presented.) –Fe (Formula presented.) O (Formula presented.). In particular, new activity–composition relations are presented for silicate melt of broadly trondhjemitic–tonalitic compos..