Journal article
Synthesis, crystal structure, DFT study of m-methoxy-Nʹ-(3-methoxybenzoyl)-N-phenylbenzohydrazide
I Arshad, J Yameen, A Saeed, JM White, F Albericio
Crystals | MDPI AG | Published : 2017
DOI: 10.3390/cryst7010019
Abstract
The crystal structure of m-methoxy-Nʹ-(m-anisoyl)-N-phenylbenzohydrazide has been determined by means of single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic space group P 21/c with unit cell parameters: a = 8.7338(1), b = 24.5602(3), c = 9.6929(1) Å, β = 113.186(2)°, V = 1911.23(4) Å3, Z = 4. The dihedral angles between the mean plane of the central benzene ring and two terminal aromatic rings are 72.44(4)° and 89.90(4)°, respectively. The two methoxyphenyl rings are orthogonal with a dihedral angle of 89.74(4)°. The crystal packing is stabilized by a combination of N–H ⋯ O intermolecular hydrogen bonding and weak intermolecular C–H ⋯ O interactions. The X-ray..
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Funding Acknowledgements
Ifzan Arshad acknowledges the financial support of this research by the Higher Education Commission of Pakistan by the Indigenous Fellowship. Fernando Albericio thanks the National Research Foundation (South Africa) for financial support.