Journal article
Spin crossover in co-crystallised 2 1 cis trans [FeII(pldpt) 2(NCS)2] occurs only in of the iron centres
JA Kitchen, GNL Jameson, JL Tallon, S Brooker
Chemical Communications | ROYAL SOC CHEMISTRY | Published : 2010
DOI: 10.1039/b927036a
Abstract
The first spin crossover (SCO) active sample of co-crystallised stereoisomers (cis trans, 2 1) is fully high spin (HS) at room temperature but displays temperature mediated SCO in which only a third of the iron(ii) centres change spin state. © The Royal Society of Chemistry 2010.
Grants
Funding Acknowledgements
This work was supported by the University of Otago, the Marsden Fund and the MacDiarmid Institute for Advanced Materials and Nanotechnology. We thank the Tertiary Education Commission (NZ) for the award of a Bright Futures Top Achiever Doctoral Scholarship to JAK. We are grateful to Dr S. Narayanaswamy (IRL) for his assistance with collecting the magnetic data.