Highly Fluorescent Pyridinium Betaines for Light Harvesting
Jingjing Xu, Bolong Zhang, Marina Jansen, Lars Goerigk, Wallace WH Wong, Chris Ritchie
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | WILEY-V C H VERLAG GMBH | Published : 2017
We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light-harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization, and wavefunction-based quantum-chemical studies of five cyclobetaines. The performance of an LSC device incorporating one of these cyclobetaines is shown to be comparable to state-of-the-art devices.
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Awarded by ARC
This work was made possible by support from the Australian Renewable Energy Agency (ARENA), which funds the project grants within the Australian Centre for Advanced Photovoltaics. We thank the ARC for financial support through the grants DE140100550 (to L.G.), CE170100026 and FT130100500 (to W.W.H.W), and DE130100615 (to C.R.). L.G. also thanks The University of Melbourne for additional financial support (RGSS2016), and the NCI and VLSCI for computing time. Responsibility for the views, information, or advice expressed herein is not accepted by the Australian Government.