Journal article

Applications of molybdenum-95 n.m.r. spectroscopy. VI: 95mo and 13c n.m.r. of certain cis-dioxomolybdenum(vi) compounds and related species. the crystal and molecular structure of bis(n, n-diethylhydroxylamido(1-)-o, n)- disulfidomolybdenum(vi) hemibenzene

SF Gheller, TW Hambley, PR Traill, RTC Brownlee, JO Maxwell, MR Snow, AG Wedd

Australian Journal of Chemistry | Published : 1982

Abstract

The 95MO n.m.r. spectra of a series of compounds containing the fac-[MoVIO3] and cis-[ MoVIO2] units are reported, together with those for the series [MoX2(R2NO)2] (X = O or S; R = Et, PhCH2). Trends in the data are discussed. The stereochemistry in solution of certain of the cis-dioxo species is assigned by means of 13C n.m.r. spectroscopy. The crystal and molecular structure of [MoS2(Et2NO)2],0.5C6H6 has been determined by X-ray crystallography. The steric and electronic requirements of the terminal sulfide ligands significantly affect the detailed coordination geometry relative to that observed for the dioxo analogue [MoO2(Et2NO)2]. Crystal data: a 10.162(2), b 11.836(2), c 14.437(2) �, β..

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