Journal article
Self-assembly of a mixed-valence FeII-FeIII tetranuclear star
D Sertphon, P Harding, KS Murray, B Moubaraki, NF Chilton, S Hill, J Marbey, H Adams, CG Davies, GNL Jameson, DJ Harding
Dalton Transactions | ROYAL SOC CHEMISTRY | Published : 2018
DOI: 10.1039/c8dt01241e
Abstract
A unique self-assembled mixed-valence FeII-FeIII tetranuclear star has been comprehensively characterised showing a large magnetic anisotropy at the peripheral FeII centres, ferromagnetic coupling between the iron centres and field-induced SMM behaviour.
Grants
Awarded by National Science Foundation
Funding Acknowledgements
We thank the Thailand Research Fund (RSA5580028 and RSA5880048), the Australian Research Council (DP140101013) and the Ramsay Memorial Trust (fellowship to NFC) for funding this research. We also thank the Thailand Research Fund for financial support in the form of a Royal Golden Jubilee scholarship to DS (PHD/0135/2554). A portion of this work was performed at the National High Magnetic Field Laboratory (NHMFL), which is supported by the NSF (DMR-1157490) and the State of Florida. SH also acknowledges the support from the NSF (DMR-1610226).