Journal article
The stabilization of gallane and indane by a ring expanded carbene
Anthony R Leverett, Alasdair I McKay, Marcus L Cole
DALTON TRANSACTIONS | ROYAL SOC CHEMISTRY | Published : 2015
DOI: 10.1039/c4dt03489a
Abstract
7Dipp Complexes of the group 13 binary hydrides GaH3 and InH3 have been prepared. Both adducts possess excellent thermal stability in the solid state but decompose readily in solution at ambient temperature. The presence of short M-H···H-CAlkyl distances in the structures of both [MH3(7Dipp)] complexes is discussed.
Grants
Awarded by Australian Research Council
Funding Acknowledgements
The authors would like to acknowledge the Australian Research Council for partial funding of this research (DP110104759) and the Australian Commonwealth for the provision of Australian Postgraduate Awards (ARL, AIM).