Modulation of sigma-Alkane Interactions in [Rh(L-2)(alkane)( ) Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to eta(2), eta(2)-sigma-Alkane Rh(I), eta(1)-sigma-Alkane Rh(III) Complexes, and Alkane Encapsulation
Antonio J Martinez-Martinez, Bengt E Tegner, Alasdair I McKay, Alexander J Bukvic, Nicholas H Rees, Graham J Tizzard, Simon J Coles, Mark R Warren, Stuart A Macgregor, Andrew S Weller
Journal of the American Chemical Society | AMER CHEMICAL SOC | Published : 2018
Awarded by EPSRC
Awarded by Leverhulme Trust
SCG Chemicals Co. Ltd., the EPSRC EP/M024210/1, and the Leverhulme Trust (RPG-2015-447) are acknowledged. This work used the ARCHER UK National Supercomputing Service (http://www.archer.ac.uk).We also acknowledge Professors J. Brown (Oxford) and D. Heller (Leibniz-Institut fur Katalyse) for helpful discussions.