Composition-tunable synthesis of Pt-Cu octahedral alloy nanocrystals from PtCu to PtCu3 via underpotential-deposition-like process and their electro-catalytic properties
Yanyan Jia, Jingyun Su, Zhibin Chen, Kai Tan, Qiaoli Chen, Zhenming Cao, Yaqi Jiang, Zhaoxiong Xie, Lansun Zheng
RSC ADVANCES | ROYAL SOC CHEMISTRY | Published : 2015
Bimetallic alloy nanocrystals (NCs) have received great attention because their physical and chemical properties greatly depend on their composition and structure. However, simultaneous control of the composition and surface structure (or morphology) of metal alloy NCs is challenging due to differences in standard redox potential (SRP). According to our previous research, well-shaped and composition-tunable Pt-Cu alloy NCs can be controlled in mild reduction conditions. However, the content of Cu in the as-prepared Pt-Cu alloy NCs cannot exceed 50% using N,N-dimethylformamide (DMF) as the weak reductant. In this paper, we reported a successful synthesis of the octahedral Pt-Cu bimetallic all..View full abstract
Awarded by National Basic Research Program of China
Awarded by National Natural Science Foundation of China
Awarded by Natural Science Foundation of Fujian Province of China
This work was supported by the National Basic Research Program of China (grants 2011CBA00508 and 2015CB932301), the National Natural Science Foundation of China (grants 21131005, 21333008, and J1310024), and the Natural Science Foundation of Fujian Province of China (no. 2014J01058).