Journal article

Tuning the Mechanical Behavior of Metal-Phenolic Networks through Building Block Composition

Gyeongwon Yun, Joseph J Richardson, Matthew Biviano, Frank Caruso

ACS APPLIED MATERIALS & INTERFACES | AMER CHEMICAL SOC | Published : 2019

Abstract

Metal-phenolic networks (MPNs) are an emerging class of functional metal-organic materials with a high degree of modularity in terms of the choice of metal ion, phenolic ligand, and assembly method. Although various applications, including drug delivery, imaging, and catalysis, have been studied with MPNs, in the form of films and capsules, the influence of metals and organic building blocks on their mechanical properties is poorly understood. Herein, we demonstrate that the mechanical properties of MPNs can be tuned through choice of the metal ion and/or phenolic ligand. Specifically, the pH of the metal ion solution and/or size of phenolic ligand influence the Young's modulus ( EY) of MPNs..

View full abstract

Grants

Awarded by ARC Centre of Excellence in Convergent Bio-Nano Science and Technology


Awarded by ARC Discovery Project


Awarded by NHMRC Senior Principal Research Fellowship


Funding Acknowledgements

This research was conducted and funded by the ARC Centre of Excellence in Convergent Bio-Nano Science and Technology (CE140100036) and an ARC Discovery Project (DP170103331). F.C. acknowledges the award of an NHMRC Senior Principal Research Fellowship (APP1135806). This work was performed in part at the Materials Characterisation and Fabrication Platform at The University of Melbourne and on the SAXS/WAXS beamline of the Australian Synchrotron, part of ANSTO.