Erratum: Synthetic β-1,2-mannosyloxymannitol glycolipid from the fungus malassezia pachydermatis signals through human mincle (Journal of Organic Chemistry (2019) 84:11 (6788-6797) DOI: 10.1021/acs.joc.9b00544)

Abstract

Several errors have been inadvertently made in the representation of the stereochemistry of the 10-oxystearic acid residue in compounds 17, 18, 19, and 44-2, and in the naming of compounds 3, 4, 8, 10, 11, 12, 13, 14, 15, 17, 18, 19, and 44-2. In all cases the stereochemistry is 10-(R). The corrected names are M e t h y l ( R ) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß - D - mannopyranosyloxy)stearate (3) Methyl (R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (4) Methyl (R)-10-(2-O-acetyl-3,4,6-tri-O-benzyl-ß-Dglucopyranosyloxy) stearate (8) Methyl (R)-10-(3,4,6-tri-O-benzyl-ß-D-glucopyranosyloxy)- stearate (9) M e t h ..