Cage dynamics leads to double relaxation of the intermediate scattering function in a binary colloidal system

Abstract

A system of binary colloids where one fraction of particles is aggregating by forming irreversible bonds and the other fraction of particles only interacts as hard spheres, is simulated using Brownian cluster dynamics. These aggregating species always formed percolating clusters for the case of diffusing hard spheres while for the static case, formation of percolating clusters depended on the fraction of static hard spheres in the system. The dynamics of the hard spheres inside the percolating clusters was studied by restarting the simulation after the kinetics of aggregation was arrested. Two cases were studied, one where the percolated particles moved within the bonds or cage dynamics was ..