Journal article

High-throughput CO2 capture using PIM-1@MOF based thin film composite membranes

M Liu, MD Nothling, PA Webley, J Jin, Q Fu, GG Qiao

Chemical Engineering Journal | Elsevier | Published : 2020

Abstract

Carbon capture from power plants represents a powerful technique to mitigate increasing greenhouse gas emissions. In this work, we describe a thin film composite (TFC) membrane incorporating a polymer of intrinsic microporosity (PIM-1) and metal organic framework (MOF) nanoparticles for post-combustion CO2 capture. The novel TFC membrane design consists of three layers: (1) a CO2 selective layer composed of a PIM-1@MOF mixed matrix; (2) an ultrapermeable PDMS gutter layer doped with MOF nanosheets; and (3) a porous polymeric substrate. Notably, the PDMS@MOF gutter layer incorporating amorphous nanosheets provides a CO2 permeance of 10,000–11,000 GPU, suggesting less gas transport resistance ..

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Grants

Awarded by Australian Research Council


Funding Acknowledgements

The authors appreciate the Bio21 Advanced Microscopy Facility for the assistance with material characterization and Dr. Gan Lin for the DLS tests. Min Liu acknowledges support from the China Scholarship Council - The University of Melbourne Scholarship (201606260063), Particulate Fluids Processing Centre (PFPC), and Salis Institute (Steps to Independence Grant). Qiang Fu acknowledges the Australian Research Council under the Future Fellowship (FT180100312).