Photochemical upconversion of near-infrared light from below the silicon bandgap

Abstract

Photochemical upconversion is a strategy for converting infrared light into more energetic, visible light, with potential applications ranging from biological imaging and drug delivery to photovoltaics and photocatalysis. Although systems have been developed for upconverting light from photon energies in the near-infrared, upconversion from below the silicon bandgap has been out of reach. Here, we demonstrate an upconversion composition using PbS semiconductor nanocrystal sensitizers that absorb photons below the bandgap of silicon and populate violanthrone triplet states below the singlet oxygen energy. The triplet-state violanthrone chromophores luminesce in the visible spectrum following ..