Journal article

Competitive Supramolecular Associations Mediate the Viscoelasticity of Binary Hydrogels

E Vereroudakis, M Bantawa, RPM Lafleur, D Parisi, NM Matsumoto, JW Peeters, E Del Gado, EW Meijer, D Vlassopoulos

ACS Central Science | American Chemical Society | Published : 2020


Supramolecular polymers are known to form strong and resilient hydrogels which can take up large amounts of water while exhibiting ease of processing and self-healing. They also possess similarities with networks of biological macromolecules. The combination of these features makes supramolecular polymers ideal candidates for studying mechanisms and consequences of self-assembly, which are relevant to biological materials. At the same time, this renders investigations of mixed hydrogels based on different supramolecular compounds necessary, since this substantially widens their applicability. Here, we address unusual viscoelastic properties of a class of binary hydrogels made by mixing fibri..

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University of Melbourne Researchers


Awarded by European Commission (Horizon2020-INFRAIA-2016-1, EUSMI grant)

Awarded by Dutch Ministry of Education, Culture and Science

Awarded by NWO/DPI program NEWPOL

Awarded by National Science Foundation

Awarded by European Commission (MSCA-ITN-2014-DODYNET)

Funding Acknowledgements

We like to thank the ICMS Animation Studio for the artwork and Xianwen Lou for assistance with HDX-MS experiments. Financial support has been received by the European Commission (Horizon2020-INFRAIA-2016-1, EUSMI grant no. 731019; MSCA-ITN-2014-DODYNET, grant no. 765811), the Dutch Ministry of Education, Culture and Science (Gravity program 024.001.035) and the NWO/DPI program NEWPOL (project 731.015.503). E.D.G. and D.V. would like to acknowledge initial support by the National Science Foundation under Grant No. NSF PHY-1748958 in the context of the 2018 "Physics of Dense Suspensions" program at KITP.