Journal article
α-Allylation of Carbonyl Compounds via Silyl Enol Ethers and Silyl Ketene Acetals using a Hypervalent Iodine Reagent
RM Moriarty, WR Epa, O Prakash
Journal of Chemical Research Part S | Royal Society of Chemistry (RSC) | Published : 1997
DOI: 10.1039/a701224a
Abstract
Oxidation of allyltrimethylsilane with iodosobenzene and trimethylsilyl trifluoromethanesulfonate followed by treatment with trimethylsilyl enol ethers of ketones or trimethylsilyl ketene acetals of esters/lactones provides a new method for the α-allylation of the corresponding carbonyl compounds.