Zinc(II) complexes derived from 2-formylpyridine nicotinoyl hydrazone as organic blocker: Syntheses, crystal architectures, Hirshfeld surface analyses and DFT studies
Ghodrat Mahmoudi, Habibar Chowdhury, Barindra Kumar Ghosh, Maciej Kubicki, Agata Bartyzel, Jonathan M White, Ibon Alkorta, Atash Gurbanov, Damir A Safin
JOURNAL OF MOLECULAR STRUCTURE | ELSEVIER | Published : 2021
In this work we report new discrete mononucler heteroleptic zinc(II) halido complexes of the type [Zn(Hal)2HL] (Hal = Cl, 1; Br, 2) and zinc(II) pseudohalido complex [Zn(NCS)2HL]·1.5MeOH (3·1.5MeOH) (HL = 2-formylpyridine nicotinoyl hydrazone). Single crystal X-ray diffraction revealed that in the structures of complexes 1–3, the Zn(II) metal atom is in a five-coordinated coordination environment and adopts a distorted square pyramidal chromophore, formed by one N2O tridentate chelator HL and two halides or thiocyanates, respectively. All complexes display a very similar molecular structure and complexes 1 and 2 are fully isostructural. Crystal packing of 1 and 2 is mainly dictated by the bi..View full abstract
Awarded by Fundacao para a Ciencia e a Tecnologia (FCT, Portugal)
Awarded by Instituto Superior Tecnico
This work has been partially supported by the Fundacao para a Ciencia e a Tecnologia (FCT, Portugal) 2020-2023 multiannual funding to Centro de Quimica Estrutural (project UIDB/00100/2020). A.V. Gurbanov acknowledges the FCT and Instituto Superior Tecnico (DL 57/2016 and L 57/2017 Program, Contract no: IST-ID/110/2018).