Journal article
A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii).
Moya A Hay, Arup Sarkar, Gavin A Craig, Katie ER Marriott, Claire Wilson, Gopalan Rajaraman, Mark Murrie
Chemical Communications | Royal Society of Chemistry | Published : 2020
DOI: 10.1039/d0cc02382e
Abstract
The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = -27.5 cm-1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.
Grants
Awarded by Engineering and Physical Sciences Research Council