Cobalt recovery from the stripping solution of spent lithium-ion battery by a three-dimensional microbial fuel cell

Abstract

Cobalt (Co) recycling from the spent LIBs not only favors the ecological protection also meets the supply chain of Co in the international market. In this research, a three-dimensional microbial-fuel-cell (3D-MFC) two-chamber system with granular activated carbon (GAC) microelectrodes was constructed to remove and recover Co from the stripping cobalt sulfate solution. The 3D bio-electrochemical (BE) system exhibited the largest voltage output and power production at 12th day during the acclimation, achieving the maximum power densities (W/m ) of 6.24, 10.29, 14.52, 12.59, and 8.78, respectively. The GAC prepared at 500 °C achieved highest removal and recovery efficiencies of Co in the 3D-MFC..