Journal article
Sono-Fenton Chemistry Converts Phenol and Phenyl Derivatives into Polyphenols for Engineering Surface Coatings
Hanxiao Mei, Zhiliang Gao, Kaijie Zhao, Mengqi Li, Muthupandian Ashokkumar, Aixin Song, Jiwei Cui, Frank Caruso, Jingcheng Hao
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | WILEY-V C H VERLAG GMBH | Published : 2021
Abstract
We report a sono-Fenton strategy to mediate the supramolecular assembly of metal-phenolic networks (MPNs) as substrate-independent coatings using phenol and phenyl derivatives as building blocks. The assembly process is initiated from the generation of hydroxyl radicals (. OH) using high-frequency ultrasound (412 kHz), while the metal ions synergistically participate in the production of additional . OH for hydroxylation/phenolation of phenol and phenyl derivatives via the Fenton reaction and also coordinate with the phenolic compounds for film formation. The coating strategy is applicable to various phenol and phenyl derivatives and different metal ions including FeII , FeIII , CuII , and C..
View full abstractGrants
Awarded by National Natural Science Foundation of China
Awarded by Innovation Project of Jinan Science and Technology Bureau
Awarded by Project for Scientific Research Innovation Team of Young Scholar in Colleges and Universities of Shandong Province
Awarded by Australian Research Council Centre of Excellence in Convergent Bio-Nano Science and Technology
Funding Acknowledgements
This research was funded by the National Natural Science Foundation of China (22072075, 21872085), Innovation Project of Jinan Science and Technology Bureau (2020GXRC022), and the Project for Scientific Research Innovation Team of Young Scholar in Colleges and Universities of Shandong Province (2020KJC001). This work was performed in part at the Analytical Centre for Structural Constituent and Physical Property, and the Translational Medicine Core Facility of Advanced Medical Research Institute at Shandong University. F.C. acknowledges funding from the Australian Research Council Centre of Excellence in Convergent Bio-Nano Science and Technology (CE140100036).