Synthesis and Electrochemical Characterization of Lithium Carboxylate 2D Compounds as High-Performance Anodes for Li−Ion Batteries

Abstract

The large-scale utilization of Li-ion batteries in electric vehicles requires urgent development of cost-effective and high-performance electrode materials. Herein, we report the synthesis of conjugated carboxylate (Li4C8H2O6) and non-conjugated carboxylate (Li4C4H2O6) by using a simple solvothermal method and its utilization as anode materials in Li-ion batteries. Atomic force microscopy reveals that as-prepared Li4C8H2O6 and Li4C4H2O6 possess a sheet-like morphology with a thickness of 3–5 nm. An initial discharge capacities of 251.7 mAh/g and 251.6 mAh/g at a current density of 50 mA/g can be obtained for Li4C8H2O6 and Li4C4H2O6, respectively. In addition, Li4C8H2O6 is combined with a sma..