Nanoporous Metal-Organic Framework Based on Furan-2,5-Dicarboxylic Acid with High Potential in Selective Adsorption and Separation of Gas Mixtures

Abstract

Today, due to the momentary release of carbon dioxide and increasing global heat, solutions that prevent the release of this greenhouse gas into the atmosphere are very important. In this work, a nanoporous sorbent with a 3D framework and chemical formula of [Ca1.5(FDC)1.5(DMF)] (MUT-13) (FDC2-= furan-2,5-dicarboxylate, DMF= N,N-dimethylformamide) was prepared in different synthetic routes. Single crystal of MUT-13 was identified by X-ray crystallographic analysis and other physicochemical analyses. Then, with the help of GCMC, the performance of MUT-13 was simulated in the adsorption of various gases (CO2, H2, C2H2, CH4, and N2) under different temperature and pressure conditions. Also, the..