Journal article
Crystalline Metal–Organic Framework Coatings Engineered via Metal–Phenolic Network Interfaces
T Wang, Z Lin, O Mazaheri, J Chen, W Xu, S Pan, CJ Kim, J Zhou, JJ Richardson, F Caruso
Angewandte Chemie International Edition | Published : 2024
Open access
Abstract
Crystalline metal–organic frameworks (MOFs) have garnered extensive attention owing to their highly ordered porous structure and physicochemical properties. However, their practical application often requires their integration with various substrates, which is challenging because of their weakly adhesive nature and the diversity of substrates that exhibit different properties. Herein, we report the use of amorphous metal–phenolic network coatings to facilitate the growth of crystalline MOF coatings on various particle and planar substrates. Crystalline MOFs with different metal ions and morphologies were successfully deposited on substrates (13 types) of varying sizes, shapes, and surface ch..
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Grants
Awarded by Australian Government
Funding Acknowledgements
This research was funded by the Australian Research Council (ARC) through the Discovery Project (DP240102343) Scheme. F.C. acknowledges the award of a National Health and Medical Research Council Leadership Fellowship (Grant no. GNT2016732). Z.L. acknowledges The University of Melbourne for an Early Career Researcher grant. J.J.R. is the recipient of an ARC Future Fellowship (Project no. FT210100669) funded by the Australian Government. S.P. acknowledges the National Natural Science Foundation of China (Grant no. 22378105 and 23FAA02526). This work was performed in part at the Materials Characterisation and Fabrication Platform (MCFP), Biosciences Microscopy Unit, and the Bio21 Institute at The University of Melbourne. X-ray absorption spectroscopy experiments were conducted at the Australian Synchrotron, part of ANSTO (Grant No. 18766). We acknowledge Dr. Marco Cassani, Dr. Shiyao Li, Dr. Christina Cortez-Jugo, and Dr. Yi Ju for their helpful discussions. Open Access publishing facilitated by The University of Melbourne, as part of the Wiley - The University of Melbourne agreement via the Council of Australian University Librarians.