Journal article

An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

ZF Chen, RG Xiong, BF Abrahams, XZ You, CM Che

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ROYAL SOC CHEMISTRY | Published : 2001

Abstract

The reaction of Cd(OH)2 with 3,3′-azodibenzoic acid affords an unprecedented anionic chiral diamondoid network, bis(3,3′-azodibenzoate)cadmium·(H2NMe2) · (NH4) which contains eight-coordinate cadmium and displays strong SHG response and enantioselectivity for organic amines.

University of Melbourne Researchers