Journal article
cis-[4a]-cisoid-[4a,4b]-cis-[4b]-4b,8b-Diethyl-1,3,5,7-tetramethylperhydro-1,3,5,7-tetraazabiphenylene-2,4,6,8-tetraone
C Näther, O Krüger, U Wille
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | INT UNION CRYSTALLOGRAPHY | Published : 2002
Abstract
The title compound, C16H24N4O4, was prepared by [2+2]-photocycloaddition of 1,3-dimethyl-6-ethyluracil in acetone. The structure determination was undertaken in order to determine the stereoconfiguration of the product, which could not be extracted from NMR data. However, single-crystal X-ray analysis revealed that the ethyl groups are located on the same side of the cyclobutane ring (cis) and that the monomers are oriented head-to-tail (anti).