Journal article

Diazenide and hydrazide(2-) derivatives of the [Re(CO)(3)]( ) core

R Alberto, AR Cowley, JR Dilworth, PS Donnelly, J Pratt

DALTON TRANSACTIONS | ROYAL SOC CHEMISTRY | Published : 2004

Abstract

Reaction of [ReBr3(CO)3]2- with aryldiazonium salts gives the Re(iii) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]-. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2-) derivative of the [Re(I)(CO)3]+ core.

University of Melbourne Researchers