Journal article
2:1 Ba/Ti(IV) heterobimetallic complex based on two calix[6]arenes
AJ Petrella, NK Roberts, DC Craig, CL Raston, RN Lamb
CHEMICAL COMMUNICATIONS | ROYAL SOC CHEMISTRY | Published : 2003
DOI: 10.1039/b302346j
Abstract
Reaction of p-Bu(t)-calix[6]arene with barium metal in methanol then [Ti(OPr(i))4] affords a heterobimetallic complex with a central Ti(IV) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.