Journal article

Relative importance of diffusion and reaction control during the bacterial and ferric sulphate leaching of zinc sulphide

G da Silva

HYDROMETALLURGY | ELSEVIER | Published : 2004

Abstract

A study has been undertaken on the bacterial and ferric sulphate leaching of sphalerite, with the aim of observing the relative importance of both diffusion and reaction control, across a range of operating conditions. To facilitate this kinetic analysis a mixed-control rate equation was developed based upon the shrinking particle and shrinking core models, featuring both an intrinsic rate of zinc extraction and a product layer diffusion coefficient. The ferric sulphate oxidation of a pure sphalerite sample was first studied, and the process was found to be mainly controlled by surface diffusion, thought to be due to formation of the elemental sulphur product layer. The mesophilic bacterial ..

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University of Melbourne Researchers