Journal article

An impaired mitochondrial electron transport chain increases retention of the hypoxia imaging agent diacetylbis(4-methylthiosemicarbazonato)copper II

PS Donnelly, JR Liddell, SC Lim, BM Paterson, MA Cater, MS Savva, AI Mot, JL James, IA Trounce, AR White, PJ Crouch

Proceedings of the National Academy of Sciences of the United States of America | Published : 2012

Abstract

Radiolabeled diacetylbis(4-methylthiosemicarbazonato)copper II[Cu II(atsm)] is an effective positron-emission tomography imaging agent for myocardial ischemia, hypoxic tumors, and brain disorders with regionalized oxidative stress, such as mitochondrial myopathy, encephalopathy, and lactic acidosis with stroke-like episodes (MELAS) and Parkinson's disease. An excessively elevated reductive state is common to these conditions and has been proposed as an important mechanism affecting cellular retention of Cu from Cu II(atsm). However, data from whole-cell models to demonstrate this mechanism have not yet been provided. The present study used a unique cell culture model, mitochondrial xenocybri..

View full abstract