Journal article
Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer
CS Hawes, R Babarao, MR Hill, KF White, BF Abrahams, PE Kruger
Chemical Communications | Published : 2012
DOI: 10.1039/c2cc37453f
Abstract
The synthesis, structural and gas sorption studies of a porous Cu(ii) coordination polymer featuring 1H-indazole-5-carboxylic acid (H2L) are presented. [Cu(HL)2] is a thermally and hydrolytically robust 4-connected 3D coordination polymer of NbO topology and is replete with 1D channels that permit selective and hysteretic sorption of CO2. © 2012 The Royal Society of Chemistry.
Grants
Funding Acknowledgements
The authors thank the University of Canterbury (Scholarship to C. S. H.); the Royal Society of New Zealand Marsden Fund (P. E. K) and the Science and Industry Endowment Fund (M. R. H., B. F. A.) for financial support.