Electron deficient conjugated polymers based on benzotriazole
James L Banal, Jegadesan Subbiah, Hamish Graham, Jin-Kyun Lee, Kenneth P Ghiggino, Wallace WH Wong
POLYMER CHEMISTRY | ROYAL SOC CHEMISTRY | Published : 2013
A series of solution processable conjugated polymers containing the benzotriazole unit have been synthesized and studied. The benzotriazole unit can be considered a moderately electron deficient building block that can readily incorporate a convenient alkyl substituent for solution processability. By varying the electron accepting strength of co-monomer partners, a series of polymers with different photophysical properties were obtained. Some polymers exhibit relatively high fluorescence quantum yields while others were able to quench the fluorescence of electron donor polymers in blends consistent with their ability to act as electron acceptors. The performance of these polymers as the acti..View full abstract
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Awarded by Australian Research Council
Awarded by National Research Foundation of Korea
This work was made possible by support from the Australian Solar Institute (Fellowship for W. W. H. Wong and project grant), Australian Research Council (DP0877325, DP0986166), the Victorian Organic Solar Cell Consortium, the Victorian State Government Department of Business Innovation (Victorian Science Agenda) and Department of Primary Industries (Energy Technology Innovation Strategy). JKL thanks the National Research Foundation of Korea (Grant no. 2011-0012274) funded by the Korean government (MEST) and Inha University.