Redox Activity and Two-Step Valence Tautomerism in a Family of Dinuclear Cobalt Complexes with a Spiroconjugated Bis(dioxolene) Ligand
Kerwyn G Alley, Giordano Poneti, Peter SD Robinson, Ayman Nafady, Boujemaa Moubaraki, Jade B Aitken, Simon C Drew, Chris Ritchie, Brendan F Abrahams, Rosalie K Hocking, Keith S Murray, Alan M Bond, Hugh H Harris, Lorenzo Sorace, Colette Boskovic
Journal of the American Chemical Society | AMER CHEMICAL SOC | Published : 2013
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This research was funded by the Australian Research Council (separate Discovery Grants to C.B. and KS.M.); G.P. and L.S. thank the European Research Council for funding through ERC-AdG MolNanoM@S. C.B. thanks Prof. N. Frank for helpful discussions. L.S. and G.P. thank Prof. A. Dei for fruitful discussions and suggestions and Dr.ssa M. C. Baratto (University Of Siena) for assistance in recording S-band spectra. Portions of this work were performed at the XAS beamline at the Australian Synchrotron.